Fourth, in the automotive fuel cell Motorcycles
China’s fuel cell research began in 1958, the 70’s in the aerospace industry, driven by fuel-cell research showed the first climax. “Ninth Five-Year Plan” period, the Ministry of Science and Technology, Chinese Academy of Sciences of fuel cell technology with the inclusion of “scientific research” a major cause of development projects, the goal is to use our advantages in resources, starting from a high starting point to enhance innovation. In the “Ninth Five-Year Plan” period, China’s fuel cell technology development closer to international standards. The elements of a “proton exchange membrane fuel cell technology”, “molten carbonate fuel cell technology” and “solid oxide fuel cell technology,” the three projects, which for the electric car “5kW proton exchange membrane fuel cell” as developed focus. This task by the Chinese Academy of Sciences and the Institute to assume a number of departments, what the target had been fully achieved.
In the proton exchange membrane fuel cell (PEMFC), the China research and development of these batteries have reached the skill level can be loaded, you can compete with developed countries in the world, but also in market share, it can be and able to occupy a certain proportion. Since the proton exchange membrane fuel cell as a “Ninth Five-Year” plan focuses on scientific and technological projects, the Dalian Institute of Chemical Physics, as the lead units across the country carried out a comprehensive proton exchange membrane fuel cell battery materials and battery systems research, great progress has been made, have assembled more than 100 watts, 1kW ~ 2kW, 5kW, 10kW to 30kW battery and battery system. 5kW battery pack inside the humidifier, including part of its power to weight ratio 100W/kg, smaller than the power of 300W / L. Proton exchange membrane fuel cell bike has been successfully developed, have been developed for electric bicycle 200w fuel cell system. From 6 5kW battery pack consisting of 30kW battery system has been successfully used for China’s first fuel cell power source minibus. Loading the battery maximum output power up to 46kw. At present, the vehicle a top speed of 60.6km / h, for fuel cell electric vehicles and hybrid electric vehicle development and lay a good foundation. The overall performance of the cell stack is equivalent to Mercedes-Benz, Ford and Canada jointly developed Balad MK7 proton exchange membrane fuel cell electric vehicle level. “Tenth Five-Year” period, the State Ministry of Science and Technology to fuel cell electric vehicles as the national “863″ program, China’s ongoing high-power proton exchange membrane fuel cell group to develop and fuel cell engine system integration studies. It is reported that Sino-US cooperation, “China’s commercialization of fuel cell bus demonstration projects” have been implemented in Beijing and Shanghai, respectively, choosing a bus route to carry out demonstration tests. The project includes not only fuel cell vehicle itself, will also fuel cell commercialization process of various infrastructure, capacity-building, training for a full range of test model, which will greatly promote China’s commercial fuel cell vehicle development progress, to industry estimates, after 10 years of China’s fuel cell industry is expected to form a vapor.
1, fuel cell (PEMFC) applications in the automotive
Fuel cells used in vehicles as early as the 20th century in the 50’s General Electric company invented proton exchange membrane fuel cell. At present, this fuel cell is the most car companies prefer to use a class of fuel cells, used to replace the original use of the internal combustion engine. Proton exchange membrane fuel cell is also called polymer electrolyte membrane, or solid polymer electrolyte membrane, or polymer electrolyte membrane fuel cell.
Proton exchange membrane fuel cell
In the proton exchange membrane fuel cell, the electrolyte is a thin polymer membrane, such as poly [perfluoro methyl] acid (poly [perfluoro sulphonic] acid), and protons to penetrate, but not conductive NafionTM, and basic by carbon electrode group Cheng. Inflow of hydrogen fuel cells reach the anode, cracking into hydrogen ions (protons) and electronic. Hydrogen ions through the electrolyte to infiltrate into the cathode, and the electronic network through an external flow of electricity. To air in the form of oxygen supply to the cathode, and electronic and hydrogen ions combine to form water. In the electrode these reactions are as follows:
Anode: 2H2 → 4H + + 4e -
Cathode: O2 + 4H + + 4e-→ 2 H2O
Overall: 2H2 + O2 → 2 H2O + energy
Proton exchange membrane fuel cell operating temperature is about 80 ℃. In such a low temperature, the electrochemical reaction can be carried out normally slow, usually with each electrode to a thin layer of platinum catalyst.
This electrode / electrolyte devices are often referred to as membrane electrode assembly (MEA), its caught in the middle of two field flow plates will be able to constitute the fuel cell. Both boards have a trench will be directed to the electrodes of fuel, but also through the membrane electrode assembly conductive. Each cell can produce about 0.7 volts of electricity, enough for the use of a lighting bulbs. Drive a car you will need about 300 volts of electricity. In order to obtain a higher voltage, will be more than a single battery can be formed in series with people known as the fuel cell memory.
Proton exchange membrane fuel cell has many features, has therefore become an ideal vehicle energy, it can replace the rechargeable batteries.
It at a lower temperature, so in cold conditions, a prompt start. Its high power density, so its size is relatively small. In addition, the high efficiency of the battery can get 40 to 50% of the maximum theoretical voltage, and can quickly and in accordance with the needs of electricity to change its output. When a car to use methanol or natural gas reforming hydrogen fuel cells as fuel instead of gasoline internal combustion engine, its carbon dioxide emissions can be reduced as much as 72 percent, and the efficiency of internal combustion engine, compared to about 25 percent, their efficiency can be as high as 60%. Methanol fuel cells for fuel, the fuel utilization rate is 1.76 times that of diesel fuel. The only potential problem is the quality of fuel, in order to avoid such a low-temperature catalyst to be contaminated, proton exchange membrane fuel cells do not have to use hydrogen fuel pollution.
At present, all over the world, in the Legislative forced car manufacturers will be able to greatly reduce the emissions limits of vehicles, proton exchange membrane fuel cell for such demands have led to substantial opportunities. Now, the majority of vehicle manufacturers, as the proton exchange membrane fuel cell for the internal combustion engine successor. In this process, the use of different vehicles and the use of different parts of the trial goes smoothly, using proton exchange membrane fuel cell buses provide the impetus for the pilot in Vancouver and Chicago have been a success. Germany’s cities also conducted a similar test, there are dozens of European cities will also be tested on the bus, London and California, will also be planning to carry out tests on small vehicles. At present, can produce 50 kW of electricity demonstration unit has been in use, can produce up to 250 kW device is also being developed.
2, fuel cell applications in the motorcycle
Development of fuel cell motorcycle, in fact, its core technologies - fuel cell research and development. Hydrogen is the only fuel cell in the direct application of the fuel, but nature does not hydrogen gas resources, can only come from other forms of energy such as natural gas, liquefied petroleum gas, gasoline, diesel, coal, biomass and alcohol, the use of all avenues for produced. However, all avenues are not feasible, the cost is not low. Of particular importance is still unable to break through the technical bottleneck, and its liquid hydrogen fuel Preparation, storage, transport and to add is a big problem. Therefore, to seek to substitute for direct use of hydrogen fuel cells and other fuel, thereby reducing the fuel cell system size and cost, fuel cell motorcycle is the focus of the study. Tests confirmed that methanol is an ideal alternative fuel. Because methanol fuel only to generate carbon dioxide and water, and methanol is the simplest of liquid organic compounds, in the market a complete sales network, storage security, and easy to carry. At the same time, as a result of motorcycle power only 1.5 ~ 3kw, will have a direct methanol fuel cell used in motorcycle is possible. Therefore, the people’s direct methanol fuel cell was very interested.
Direct methanol fuel cells do not need re-engineering and direct methanol as fuel. Methanol in the anode into carbon dioxide and hydrogen, as the standard proton exchange membrane fuel cell, the reaction of hydrogen with oxygen. In the electrode these reactions are as follows:
Anodic reaction: CH3 OH + H2O → CO2 + 6H + + 6e -
Cathode reaction: O2 + 6H + + 6e-→ 3 H2O
Cell reaction: CH3OH + O2 → CO2 + 2 H2O
Such expectations of the work of the battery temperature is 120 ℃, than the standard of the proton exchange membrane fuel cell is slightly higher, its efficiency is about 40%. Its drawback is that when the low temperature methanol converted to hydrogen and carbon dioxide than when conventional proton exchange membrane fuel cells need more platinum catalyst. However, this increase in cost can be due to easy access to liquid fuel and can Needless to revitalize the work of dwarfs.
To sum up, from the world’s fuel cell to see the momentum of rapid development, the first decade of this century will be the provider of fuel cell technology, an important stage of industrialization, its technical relevance, the cost of production, such as a major breakthrough was achieved. Efficient, environmentally friendly fuel cell vehicles produced, and commercialization will certainly become an irresistible general trend
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